disodium (4E)-4-[(2-arsonophenyl)hydrazono]-3-oxo-3,4-dihydronaphthalene-2,7-disulfonate
Thorin I
CAS: 3688-92-4
Molecular Formula: C16H11AsN2Na2O10S2
disodium (4E)-4-[(2-arsonophenyl)hydrazono]-3-oxo-3,4-dihydronaphthalene-2,7-disulfonate - Names and Identifiers
| Name | Thorin I |
| Synonyms | APANS ASPAN Thorin I DISODIUM-1-(O-ARSONOPHENYLAZO)-2-NAPHTHOL-3,6-DISULFONIC ACID 1-(O-ARSONOPHENYLAZO)-2-NAPHTHOL-3,6-DISULFONIC ACID DISODIUM SALT 2-(3,6-DISULFO-2-HYDROXY-1-NAPHTHYLAZO)BENZENE ARSONIC ACID, DISODIUM 2-(2-HYDROXY-3,6-DISULFO-1-NAPHTHYLAZO)PHENYLARSONIC ACID DISODIUM SALT 2-[(2-HYDROXY-3,6-DISULFO-1-NAPHTHYL)AZO]BENZENEARSONIC ACID DISODIUM SALT 2-(3,6-Disulfo-2-hydroxy-1-naphthylazo)benzene arsonic acid, disodium salt 2-(2-HYDROXY-3,6-DISULFO-1-NAPHTHYLAZO)-BENZENE-ARSONIC ACID SODIUM SALT OCTAHYDRATE disodium (4E)-4-[(2-arsonophenyl)hydrazono]-3-oxo-3,4-dihydronaphthalene-2,7-disulfonate |
| CAS | 3688-92-4 |
| EINECS | 222-993-1 |
| InChI | InChI=1/C16H13AsN2O10S2.2Na/c20-16-14(31(27,28)29)8-9-7-10(30(24,25)26)5-6-11(9)15(16)19-18-13-4-2-1-3-12(13)17(21,22)23;;/h1-8,18H,(H2,21,22,23)(H,24,25,26)(H,27,28,29);;/q;2*+1/p-2/b19-15+; |
| InChIKey | DCSRPHQBFSYJNN-BUFQOAPZSA-L |
disodium (4E)-4-[(2-arsonophenyl)hydrazono]-3-oxo-3,4-dihydronaphthalene-2,7-disulfonate - Physico-chemical Properties
| Molecular Formula | C16H11AsN2Na2O10S2 |
| Molar Mass | 576.3 |
| Melting Point | >300°C |
| Water Solubility | Soluble in water. |
| Appearance | powder to crystal |
| Color | Orange to Brown to Dark red |
| pKa | pK1:3.7;pK2:8.3;pK3:11.8 (25°C) |
| PH | 6.1 (10g/l, H2O, 20℃) |
| Storage Condition | Store at +5°C to +30°C. |
disodium (4E)-4-[(2-arsonophenyl)hydrazono]-3-oxo-3,4-dihydronaphthalene-2,7-disulfonate - Risk and Safety
| Risk Codes | R23/25 - Toxic by inhalation and if swallowed. R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. |
| Safety Description | S20/21 - S28 - After contact with skin, wash immediately with plenty of soap-suds. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S60 - This material and its container must be disposed of as hazardous waste. S61 - Avoid release to the environment. Refer to special instructions / safety data sheets. |
| UN IDs | UN 3465 6.1/PG 3 |
| WGK Germany | 3 |
| TSCA | Yes |
| HS Code | 29270000 |
| Hazard Class | 6.1(a) |
| Packing Group | II |
disodium (4E)-4-[(2-arsonophenyl)hydrazono]-3-oxo-3,4-dihydronaphthalene-2,7-disulfonate - Introduction
Thorin I(Thorin I) is an organic compound with the following properties:
1. Appearance: Thorin I is a yellow powdery solid.
2. Solubility: It can be dissolved in water, but insoluble in organic solvents.
3. Stability: The compound is relatively stable at room temperature and stored for a long time under dry conditions.
Thorin I is mainly used in the field of analytical chemistry and is often used as an analytical reagent for cobalt. It can form a blue complex with cobalt ions, and the content of cobalt can be determined by colorimetry or fluorescence method.
The method of preparing Thorin I is as follows:
1. First, 2-naphthol reacts with aniline to form aniline arsenate.
2. Then, 1-(2-arsic acid phenylazo)-2-naphthol -3,6-disulfonic acid was generated by coupling reaction of arsic acid aniline and o-thiophenol acid.
3. Finally, the product is reacted with the sodium salt to form Thorin I.
The following safety information is required when using, storing and handling Thorin I:
1. avoid contact with skin and eyes, such as accidental contact, should immediately rinse with plenty of water.
2. in the use of the process to maintain good ventilation conditions.
3. Store Thorin I in a dry, cool place.
4. Isolated from other chemicals, heat and fire sources to prevent the risk of fire or explosion.
5. If accidentally swallowed or inhaled, seek medical attention immediately.
1. Appearance: Thorin I is a yellow powdery solid.
2. Solubility: It can be dissolved in water, but insoluble in organic solvents.
3. Stability: The compound is relatively stable at room temperature and stored for a long time under dry conditions.
Thorin I is mainly used in the field of analytical chemistry and is often used as an analytical reagent for cobalt. It can form a blue complex with cobalt ions, and the content of cobalt can be determined by colorimetry or fluorescence method.
The method of preparing Thorin I is as follows:
1. First, 2-naphthol reacts with aniline to form aniline arsenate.
2. Then, 1-(2-arsic acid phenylazo)-2-naphthol -3,6-disulfonic acid was generated by coupling reaction of arsic acid aniline and o-thiophenol acid.
3. Finally, the product is reacted with the sodium salt to form Thorin I.
The following safety information is required when using, storing and handling Thorin I:
1. avoid contact with skin and eyes, such as accidental contact, should immediately rinse with plenty of water.
2. in the use of the process to maintain good ventilation conditions.
3. Store Thorin I in a dry, cool place.
4. Isolated from other chemicals, heat and fire sources to prevent the risk of fire or explosion.
5. If accidentally swallowed or inhaled, seek medical attention immediately.
Last Update：2024-04-09 21:01:54
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View History
disodium (4E)-4-[(2-arsonophenyl)hydrazono]-3-oxo-3,4-dihydronaphthalene-2,7-disulfonate
Bicyclo[3.1.1]heptane-3-thiol, 6,6-dimethyl-2-methylene-
2-甲基-2-疏基硫酸脲
阿莫西林相关物质D USP标准品
α-Isoamyl-α-ethylmalonic acid diethyl ester
对硝基苯基 BETA-D-吡喃甘露糖苷
1-hydroxyethyl peroxyacetate
Undecanedioic acid, 2-octyl-, 1,11-dimethyl ester
氯化二甲基硫代氨基甲酰
6-dimethyl-5-hept-2-en-4-yne
Bicyclo[3.1.1]heptane-3-thiol, 6,6-dimethyl-2-methylene-
2-甲基-2-疏基硫酸脲
阿莫西林相关物质D USP标准品
α-Isoamyl-α-ethylmalonic acid diethyl ester
对硝基苯基 BETA-D-吡喃甘露糖苷
1-hydroxyethyl peroxyacetate
Undecanedioic acid, 2-octyl-, 1,11-dimethyl ester
氯化二甲基硫代氨基甲酰
6-dimethyl-5-hept-2-en-4-yne